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<processDataSet xmlns="http://lca.jrc.it/ILCD/Process" xmlns:common="http://lca.jrc.it/ILCD/Common" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://lca.jrc.it/ILCD/Process ../../schemas/ILCD_ProcessDataSet.xsd" locations="../ILCDLocations.xml" version="1.1">
  <processInformation>
    <dataSetInformation>
      <common:UUID>d7679212-da86-4656-b9d7-24423e64a68d</common:UUID>
      <name>
        <baseName xml:lang="en">Methylenediphenyl diisocyanate ( (p)MDI)</baseName>
        <treatmentStandardsRoutes xml:lang="en">phosgenation of methylenedianiline (MDA)</treatmentStandardsRoutes>
        <mixAndLocationTypes xml:lang="en">production mix, at plant</mixAndLocationTypes>
        <functionalUnitFlowProperties xml:lang="en">polymeric MDI ( (p)MDI)</functionalUnitFlowProperties>
      </name>
      <classificationInformation>
        <common:classification name="GaBiCategories" classes="../GaBiCategories.xml">
          <common:class level="0" classId="d9e81c75-315c-4c0f-b5d3-e1f5f03d1263">Production</common:class>
          <common:class level="1" classId="455ffb41-4777-4723-954a-492e09d7e56a">Material production</common:class>
          <common:class level="2" classId="6ef1c82c-6e31-48b6-9723-115804f34d34">Intermediate products production</common:class>
          <common:class level="3" classId="4e177fec-afa5-47a5-88bb-18cf0c3920c3">Organic intermediate products</common:class>
        </common:classification>
      </classificationInformation>
      <common:generalComment xml:lang="en">The main data source was a data collection from European producers of MDI. Primary data on gate-to-gate MDI production is derived from site-specific information for processes under operational control supplied by the participating companies of this study. Five different  MDI producers with plants in five European countries participated in the primary data collection. 90% of the European MDI production (EU-27) in 2010 is covered. The data for the upstream supply chain until the precursors are taken from the GaBi Database'11 of the software system GaBi 5. For the most relevant intermediate to the MDI process in terms of environmental aspects (aniline), a confirmation of the quality of the data and its industrial representativeness was provided by the participating member companies.
Mass allocation was applied for the production process of MDI as hydrogen chloride (HCl 100%) results as co-product.</common:generalComment>
    </dataSetInformation>
    <quantitativeReference type="Reference flow(s)">
      <referenceToReferenceFlow>93</referenceToReferenceFlow>
    </quantitativeReference>
    <time>
      <common:referenceYear>2010</common:referenceYear>
      <common:dataSetValidUntil>2022</common:dataSetValidUntil>
      <common:timeRepresentativenessDescription xml:lang="en">The LCI data for MDI production was collected as 12 month averages representing the year 2010, to compensate seasonal influence of data. Background data have reference years from 2008 to 2010. The dataset is considered to be valid until substantial technological changes in the production chain occur.</common:timeRepresentativenessDescription>
    </time>
    <geography>
      <locationOfOperationSupplyOrProduction location="EU-27">
        <descriptionOfRestrictions xml:lang="en">Primary production data for the MDI production is from five different suppliers in the EU (Germany, Belgium, Netherlands, Portugal and Hungary). Fuel and energy inputs in the system reflect average European conditions and whenever applicable, site specific conditions were applied, to reflect representative situations. Therefore, the study results are intended to be applicable within EU boundaries and in order to be applied in other regions ad-justments might be required. MDI imported into Europe was not considered in this Eco-profile.</descriptionOfRestrictions>
      </locationOfOperationSupplyOrProduction>
    </geography>
    <technology>
      <technologyDescriptionAndIncludedProcesses xml:lang="en">Commercial production of MDI involves the following key process stages.
The production of MDI involves the following major stages:
• Production of Methylenedianiline (MDA): In the production of MDI, Methylenedianiline (MDA) is formed initially through the reaction of formaldehyde with aniline in the presence of a hydrochloric acid catalyst. The percentage distribution of isomers of MDA formed during this step depends on the ratio of aniline to formaldehyde, the acid concentration, and the reaction conditions. After the reaction, the mixture is neutralised by adding caustic soda, and separates into an organic phase and an inorganic (aqueous) phase. The organic phase containing crude MDA is washed. Excess aniline from washing is isolated by distillation for recycling in the first step of the reaction. The inorganic (aqueous) phase is purified from any residual organics and discharged for further treatment or recovery.
• Phosgenation of MDA to crude MDI: During this stage phosgene is reacted with MDA in an inert solvent to produce crude MDI and a hydrogen chloride byproduct.
• Solvent Recovery and MDI Purification: Following phosgenation, when evolution of hydrogen chloride is complete and a homogeneous solution is obtained, the solvent is recovered by distillation. Purified MDI is obtained by fractional distillation, crystallization, or sublimation.
The background system is addressed as follows:  
Electricity, Thermal energy: The electricity (and thermal energy as by-product) used is modelled according to the individual country-specific situation. The country-specific modelling is achieved on multiple levels. Firstly the individual power plants in service are modelled according to the current national grid. This includes net losses and imported electricity. Second, the national emission and efficiency standards of the power plants are modelled. Third, the country-specific fuel supply (share of resources used, by import and / or domestic supply) including the country-specific properties (e.g. element and energy contents) are accounted for. Fourth, the import, transport, mining and exploration processes for the energy carrier supply chain are modelled according to the specific situation of each power-producing country. The different mining and exploration techniques (emissions and efficiencies) in the different exploration countries are accounted for according to current engineering knowledge and information.  
Steam: The steam supply is modelled according to the individual country-specific situation with regard to the technology efficiencies and energy carriers used. Efficiencies range from 85% to 95% in relation to the representative energy carrier (gas, oil, coal). Coal, crude oil and natural gas used for the generation of steam are modelled according to the specific import situation (see electricity).  
Energy carriers: Coal, crude oil, natural gas and uranium are modelled according to the specific import situation (see electricity).  
Refinery products: Diesel, gasoline, technical gases, fuel oils, basic oils and residues such as bitumen are modelled via a country-specific, refinery parameterized model. The refinery model represents the current national standard in refinery techniques (e.g. emission level, internal energy consumption,...) as well as the individual country-specific product output spectrum, which can be quite different from country to country. Hence the refinery products used show the individual country-specific use of resources. The supply of crude oil is modelled, again, according to the country-specific crude oil situation with the respective properties of the resources.</technologyDescriptionAndIncludedProcesses>
      <technologicalApplicability xml:lang="en">The major application of 4.4-MDI is as a primary feedstock for the production of rigid polyurethane foams. Such foams have good thermal insulation properties and are used worldwide in the manufac-ture of freezers and refrigerators, and in building and automotive applications.</technologicalApplicability>
      <referenceToTechnologyFlowDiagrammOrPicture refObjectId="329d5a05-6838-4394-989b-92bcaae00b8c" version="19.00.000" type="source data set" uri="../sources/329d5a05-6838-4394-989b-92bcaae00b8c_19.00.000.xml">
        <common:shortDescription xml:lang="en">ISOPA_MDI Production.jpg</common:shortDescription>
      </referenceToTechnologyFlowDiagrammOrPicture>
    </technology>
    <mathematicalRelations>
      <modelDescription xml:lang="en">The calculation follows the vertical calculation methodology, i.e. that the averaging is done after modelling the specific processes. Restrictions on competition and confidentiality do not allow displaying and describing the systems and analysing details.
Mass allocation was applied both for the production process of MDI as hydrogen chloride (HCl 100%) results as co-product from both production processes. The choice on this allocation procedure took two important aspects into consideration:
• Although the primarily purpose of the plants are to produce MDI, these processes have been specifically designed not only to produce MDI in the required quality, but also to produce HCl in a quality that can be marketed, i.e. HCl is a desired co-product. Therefore the quality of the HCl is a critical aspect and influences on the process design.
• Despite of the fact that both products are sold as valuable substances, prices do not reach the same level for both cases, with higher absolute values for MDI. But as HCl would have to be neutralized and disposed if not be sold as product, the actual value of HCl cannot be expressed by the market value alone, and therefore the physical procedure (mass allocation) would most reflect the reality.</modelDescription>
    </mathematicalRelations>
  </processInformation>
  <modellingAndValidation>
    <LCIMethodAndAllocation>
      <typeOfDataSet>LCI result</typeOfDataSet>
      <LCIMethodPrinciple>Attributional</LCIMethodPrinciple>
      <deviationsFromLCIMethodPrinciple xml:lang="en">None</deviationsFromLCIMethodPrinciple>
      <LCIMethodApproaches>Allocation - market value</LCIMethodApproaches>
      <LCIMethodApproaches>Allocation - net calorific value</LCIMethodApproaches>
      <LCIMethodApproaches>Allocation - mass</LCIMethodApproaches>
      <deviationsFromLCIMethodApproaches>None</deviationsFromLCIMethodApproaches>
      <modellingConstants xml:lang="en">All data used in the calculation of the LCI results refer to net calorific value.</modellingConstants>
      <deviationsFromModellingConstants xml:lang="en">None</deviationsFromModellingConstants>
      <referenceToLCAMethodDetails refObjectId="1f39e45a-4c3d-4067-a1a9-a11db942c605" version="19.00.000" type="source data set" uri="../sources/1f39e45a-4c3d-4067-a1a9-a11db942c605_19.00.000.xml">
        <common:shortDescription xml:lang="en">Eco-profiles and Environmental Declarations, Version 2.0 (April 2011)</common:shortDescription>
      </referenceToLCAMethodDetails>
      <referenceToLCAMethodDetails refObjectId="f2b512cd-43b2-4260-9882-eebc06731274" version="19.00.000" type="source data set" uri="../sources/f2b512cd-43b2-4260-9882-eebc06731274_19.00.000.xml">
        <common:shortDescription xml:lang="en">GaBi Modelling Principles 2011</common:shortDescription>
      </referenceToLCAMethodDetails>
    </LCIMethodAndAllocation>
    <dataSourcesTreatmentAndRepresentativeness>
      <dataCutOffAndCompletenessPrinciples xml:lang="en">In the foreground processes all relevant flows were considered, trying to avoid any cut-off of material and energy flows. In single cases additives used in the MDI unit process (&lt;0.1 % m/m of product output) were neglected. In all cases it was assured that no hazardous substances or metals were present in this neglected part.
According to the GaBi Databases 2011, used in the background processes, at least 95 % of mass and energy of the input and output flows were covered and 98 % of their environmental relevance (according to expert judgment) was considered, hence an influence of cut-offs less than 1 % on the total in expected. All transports in the pre-chain contribute maximum 0.2% to the overall environmental burden. Including production the contribution of all transports is expected to be less than 1 %, thus transports are excluded from this investigation.</dataCutOffAndCompletenessPrinciples>
      <deviationsFromCutOffAndCompletenessPrinciples xml:lang="en">None</deviationsFromCutOffAndCompletenessPrinciples>
      <dataSelectionAndCombinationPrinciples xml:lang="en">90% coverage of the European industry.</dataSelectionAndCombinationPrinciples>
      <deviationsFromSelectionAndCombinationPrinciples xml:lang="en">None</deviationsFromSelectionAndCombinationPrinciples>
      <dataTreatmentAndExtrapolationsPrinciples xml:lang="en">The data set represents the specific situation in Europe, focusing on the main technologies used for producing MDI  in Europe. Primary production data for the MDI production is from five different suppliers in the EU.</dataTreatmentAndExtrapolationsPrinciples>
      <deviationsFromTreatmentAndExtrapolationPrinciples xml:lang="en">None</deviationsFromTreatmentAndExtrapolationPrinciples>
      <referenceToDataSource refObjectId="61875b4e-7249-444b-8691-e4a04e6d3c47" version="19.00.000" type="source data set" uri="../sources/61875b4e-7249-444b-8691-e4a04e6d3c47_19.00.000.xml">
        <common:shortDescription xml:lang="en">GaBi databases 2011</common:shortDescription>
      </referenceToDataSource>
      <percentageSupplyOrProductionCovered>90.0</percentageSupplyOrProductionCovered>
      <annualSupplyOrProductionVolume xml:lang="en">The considered participants covered 90% of the MDI European production in 2010.</annualSupplyOrProductionVolume>
      <samplingProcedure xml:lang="en">European producers act as a main source of data for the production of MDI on the basis of a direct questionnaire. Primary data on gate-to-gate MDI production is derived from site specific information for processes under operational control supplied by the participating companies of this study. The data for the upstream supply chain until the precursors are taken from the GaBi Database'11 of the software system GaBi 5. For the most relevant intermediate to the MDI process in terms of environmental aspects (aniline), a confirmation of the quality of the data and its industrial representativeness was provided by the participating member companies.</samplingProcedure>
      <dataCollectionPeriod xml:lang="en">2010</dataCollectionPeriod>
      <useAdviceForDataSet xml:lang="en">The LCI data set should be used for LCI/ LCA studies where MDI is used along the production chain. The major application of 4.4-MDI is as a primary feedstock for the production of rigid polyurethane foams. Such foams have good thermal insulation properties and are used worldwide in the manufac-ture of freezers and refrigerators, and in building and automotive applications.</useAdviceForDataSet>
    </dataSourcesTreatmentAndRepresentativeness>
    <completeness>
      <completenessProductModel>All relevant flows quantified</completenessProductModel>
    </completeness>
    <validation>
      <review type="Dependent internal review">
        <common:scope name="Raw data">
          <common:method name="Validation of data sources"/>
          <common:method name="Cross-check with other source"/>
          <common:method name="Expert judgment"/>
          <common:method name="Mass balance"/>
          <common:method name="Compliance with ISO 14040 to 14044"/>
        </common:scope>
        <common:scope name="Unit process(es), black box">
          <common:method name="Validation of data sources"/>
          <common:method name="Expert judgment"/>
          <common:method name="Mass balance"/>
          <common:method name="Compliance with ISO 14040 to 14044"/>
        </common:scope>
        <common:scope name="LCI results or Partly terminated system">
          <common:method name="Energy balance"/>
          <common:method name="Expert judgment"/>
          <common:method name="Mass balance"/>
          <common:method name="Documentation"/>
        </common:scope>
        <common:scope name="LCIA results">
          <common:method name="Cross-check with other source"/>
          <common:method name="Cross-check with other data set"/>
        </common:scope>
        <common:scope name="Life cycle inventory methods">
          <common:method name="Compliance with ISO 14040 to 14044"/>
        </common:scope>
        <common:dataQualityIndicators>
          <common:dataQualityIndicator name="Technological representativeness" value="Very good"/>
          <common:dataQualityIndicator name="Time representativeness" value="Very good"/>
          <common:dataQualityIndicator name="Geographical representativeness" value="Very good"/>
          <common:dataQualityIndicator name="Completeness" value="Very good"/>
          <common:dataQualityIndicator name="Precision" value="Very good"/>
          <common:dataQualityIndicator name="Methodological appropriateness and consistency" value="Very good"/>
          <common:dataQualityIndicator name="Overall quality" value="Very good"/>
        </common:dataQualityIndicators>
        <common:reviewDetails xml:lang="en">The internal review was done by several iteration steps concerning raw data validation, completeness and consistency of modelling with regard to ISO 14040 and 14044.</common:reviewDetails>
        <common:referenceToNameOfReviewerAndInstitution refObjectId="623edf96-39d1-4e6f-9892-674c7228546b" version="19.00.000" type="contact data set" uri="../contacts/623edf96-39d1-4e6f-9892-674c7228546b_19.00.000.xml">
          <common:shortDescription xml:lang="en">PE INTERNATIONAL</common:shortDescription>
        </common:referenceToNameOfReviewerAndInstitution>
        <common:otherReviewDetails xml:lang="en">The LCI method applied is in compliance with ISO 14040 and 14044. The documentation includes all relevant information in view of the data quality and scope of the application of the respective LCI result / data set. The dataset represents the state-of-the-art in view of the referenced functional unit.</common:otherReviewDetails>
      </review>
      <review type="Third party review (independent)">
        <common:scope name="Unit process(es), single operation">
          <common:method name="Expert judgment"/>
        </common:scope>
        <common:scope name="Unit process(es), black box">
          <common:method name="Cross-check with other data set"/>
        </common:scope>
        <common:scope name="LCI results or Partly terminated system">
          <common:method name="Cross-check with other data set"/>
        </common:scope>
        <common:scope name="LCIA results">
          <common:method name="Cross-check with other source"/>
        </common:scope>
        <common:scope name="Documentation">
          <common:method name="Cross-check with other source"/>
          <common:method name="Compliance with ISO 14040 to 14044"/>
        </common:scope>
        <common:scope name="Life cycle inventory methods">
          <common:method name="Cross-check with other source"/>
          <common:method name="Compliance with ISO 14040 to 14044"/>
        </common:scope>
        <common:scope name="Goal and scope definition">
          <common:method name="Cross-check with other source"/>
          <common:method name="Compliance with ISO 14040 to 14044"/>
        </common:scope>
        <common:dataQualityIndicators>
          <common:dataQualityIndicator name="Technological representativeness" value="Very good"/>
          <common:dataQualityIndicator name="Time representativeness" value="Very good"/>
          <common:dataQualityIndicator name="Geographical representativeness" value="Very good"/>
          <common:dataQualityIndicator name="Completeness" value="Very good"/>
          <common:dataQualityIndicator name="Precision" value="Very good"/>
          <common:dataQualityIndicator name="Methodological appropriateness and consistency" value="Very good"/>
          <common:dataQualityIndicator name="Overall quality" value="Very good"/>
        </common:dataQualityIndicators>
        <common:reviewDetails xml:lang="en">The project included regular milestone meetings with representatives of all participating producers and the programme manager. The reviewer participated in these meetings. In addition, a review meeting between the LCA practitioner and the reviewer was held, including a model and database review, and spot checks of data and calculations</common:reviewDetails>
        <common:referenceToNameOfReviewerAndInstitution refObjectId="f50245de-12d9-47ed-848e-5b5c078879cc" version="19.00.000" type="contact data set" uri="../contacts/f50245de-12d9-47ed-848e-5b5c078879cc_19.00.000.xml">
          <common:shortDescription xml:lang="en">DEKRA</common:shortDescription>
        </common:referenceToNameOfReviewerAndInstitution>
        <common:otherReviewDetails xml:lang="en">The LCA practitioner has demonstrated a very good competence and experience, with a track record of LCA projects in the chemical and plastics industry. A dominance analysis was conducted to identify sensitive data requirements prior to the data collection. Original data were collected for all foreground processes, while background process data were taken from the GaBi database which is likewise of good quality.
The precursor aniline was shown to have the most substantial influence on the results. Although the precision of the dataset was not formally calculated by means of a statistical analysis, it is assessed to be very good for two reasons: first, because of the clear procedure adopted, and second, because of the robustness achieved by being based upon an average of different discrete European production sites. The sites were individually analysed and specifically modelled, representing the respective technologies. The deviation among the degree of detail and consistency was found to be low.
Allocation was applied for HCl 100% partitioning parameter, following a conservative approach and reflecting the purpose of the operations.
Calculation and reporting were subject to extensive analysis and review. As a result, this dataset is assessed to be a reliable and high-quality representation of MDI production in Europe.
</common:otherReviewDetails>
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          <common:shortDescription xml:lang="en">Eco-profiles and Environmental Declarations, Version 2.0 (April 2011)</common:shortDescription>
        </common:referenceToComplianceSystem>
        <common:approvalOfOverallCompliance>Fully compliant</common:approvalOfOverallCompliance>
        <common:nomenclatureCompliance>Fully compliant</common:nomenclatureCompliance>
        <common:methodologicalCompliance>Fully compliant</common:methodologicalCompliance>
        <common:reviewCompliance>Fully compliant</common:reviewCompliance>
        <common:documentationCompliance>Fully compliant</common:documentationCompliance>
        <common:qualityCompliance>Not defined</common:qualityCompliance>
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      <compliance>
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          <common:shortDescription xml:lang="en">GaBi conformity system</common:shortDescription>
        </common:referenceToComplianceSystem>
        <common:approvalOfOverallCompliance>Fully compliant</common:approvalOfOverallCompliance>
        <common:nomenclatureCompliance>Fully compliant</common:nomenclatureCompliance>
        <common:methodologicalCompliance>Fully compliant</common:methodologicalCompliance>
        <common:reviewCompliance>Fully compliant</common:reviewCompliance>
        <common:documentationCompliance>Fully compliant</common:documentationCompliance>
        <common:qualityCompliance>Not defined</common:qualityCompliance>
      </compliance>
      <compliance>
        <common:referenceToComplianceSystem refObjectId="d92a1a12-2545-49e2-a585-55c259997756" version="19.00.000" type="source data set" uri="../sources/d92a1a12-2545-49e2-a585-55c259997756_19.00.000.xml">
          <common:shortDescription xml:lang="en">ILCD Data Network - Entry-level</common:shortDescription>
        </common:referenceToComplianceSystem>
        <common:approvalOfOverallCompliance>Not defined</common:approvalOfOverallCompliance>
        <common:nomenclatureCompliance>Not defined</common:nomenclatureCompliance>
        <common:methodologicalCompliance>Fully compliant</common:methodologicalCompliance>
        <common:reviewCompliance>Not defined</common:reviewCompliance>
        <common:documentationCompliance>Not defined</common:documentationCompliance>
        <common:qualityCompliance>Not defined</common:qualityCompliance>
      </compliance>
    </complianceDeclarations>
  </modellingAndValidation>
  <administrativeInformation>
    <common:commissionerAndGoal>
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        <common:shortDescription xml:lang="en">ISOPA</common:shortDescription>
      </common:referenceToCommissioner>
      <common:project xml:lang="en">PlasticsEurope Eco-profiles</common:project>
      <common:intendedApplications xml:lang="en">This eco-profile (LCI) is intended to be used as »cradle-to-gate« building blocks of life cycle assessment (LCA) studies of defined applications or products. LCA studies considering the full life cycle (»cradle-to-grave«) of an application or product allow for comparative assertions to be derived. It is essential to note that comparisons cannot be made at the level of the polymer or its precursors. In order to compare the performance of different materials, the whole life cycle and the effects of relevant life cycle parameters must be considered. It is intended to be used by member companies, to support product-orientated environmental management; by users of plastics, as a building block of life cycle assessment (LCA) studies of individual products; and by other interested parties, as a source of life cycle information.</common:intendedApplications>
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        <common:shortDescription xml:lang="en">PE INTERNATIONAL</common:shortDescription>
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      <common:timeStamp>2012-04-10T11:52:02+01:00</common:timeStamp>
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        <common:shortDescription xml:lang="en">ILCD format 1.1</common:shortDescription>
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        <common:shortDescription xml:lang="en">PE INTERNATIONAL</common:shortDescription>
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    <publicationAndOwnership>
      <common:dateOfLastRevision>2012-04-10T11:52:02+01:00</common:dateOfLastRevision>
      <common:dataSetVersion>00.00.000</common:dataSetVersion>
      <common:workflowAndPublicationStatus>Data set finalized; entirely published</common:workflowAndPublicationStatus>
      <common:referenceToOwnershipOfDataSet refObjectId="539e4347-e16f-471d-aa6e-2b8a053bfb00" version="19.00.000" type="contact data set" uri="../contacts/539e4347-e16f-471d-aa6e-2b8a053bfb00_19.00.000.xml">
        <common:shortDescription xml:lang="en">ISOPA</common:shortDescription>
      </common:referenceToOwnershipOfDataSet>
      <common:copyright>true</common:copyright>
      <common:licenseType>Other</common:licenseType>
      <common:accessRestrictions xml:lang="en">GaBi (source code, database including extension modules and single data sets, documentation) remains property of PE INTERNATIONAL AG. PE INTERNATIONAL AG delivers GaBi licenses comprising data storage medium and manual as ordered by the customer. The license guarantees the right of use for one installation of GaBi. Further installations using the same license are not permitted. Additional licenses are only valid if the licensee holds at least one main license. Licenses are not transferable and must only be used within the licensee's organisation. Data sets may be copied for internal use. The number of copies is restricted to the number of licenses of the software system GaBi the licensee owns. The right of use is exclusively valid for the licensee. All rights reserved.</common:accessRestrictions>
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      <referenceToFlowDataSet refObjectId="fe0acd60-3ddc-11dd-aaa4-0050c2490048" version="02.00.000" type="flow data set" uri="../flows/fe0acd60-3ddc-11dd-aaa4-0050c2490048_02.00.000.xml">
        <common:shortDescription xml:lang="en">air (Resources from air)</common:shortDescription>
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      <meanAmount>15.3941645771001</meanAmount>
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        <common:shortDescription xml:lang="en">antimony (Resources from ground)</common:shortDescription>
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    <exchange dataSetInternalID="63">
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    <exchange dataSetInternalID="64">
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      <dataSourceType>Mixed primary / secondary</dataSourceType>
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